Insulator-insulator and insulator-conductor transitions in the phase diagram of aluminium trichloride
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| Title | Insulator-insulator and insulator-conductor transitions in the phase diagram of aluminium trichloride |
| Authors | |
| Abstract | We report a classical computer-simulation study of the phase diagram of AlCl3 in the pressure-temperature (p, T) plane, showing (i) that melting from a layered crystal structure occurs into a molecular liquid at low (p, T) and into a dissociated ionic liquid at high (p, T), and (ii) that a broad transition from a molecular insulator to an ionic conductor takes place in the liquid state. |
| Publisher | Accademia Peloritana dei Pericolanti |
| Date | 2009-11-26 |
| Source | 0365-0359 |
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